Material Safety Data Sheet
1. IDENTIFICATION OF THE MIXTURE/PREPARATION AND OF THE COMPANY
| Product name: | 507BTL | Supplier: | Terraflex Reshafim Plastic Products | ||||
| Trade name and synonyms: | 150710 | Kibbutz Reshafim M.P. Beit-Shean 10905 Israel | |||||
| Chemical family: | PVC Compound | Emergency phone no. : 972-4-6065384 | |||||
| Formula: | Proprietary formulation | Fax No. : 972-4-6065116 | |||||
2. COMPOSITION/INFORMATION ON INGREDIENTS
| Substance/preparation: | preparation | |||
| Hazardous ingredient | Chemical name | Cas # | % Symbol. | R-phrase |
| Dimethyltin bis(2-ethylhexylthioglycolate) | 57583-35-4 | |||
| Mehtyltin tris(2-ethylhexylthioglycolate) | 57583-34-3 | |||
| 1 - 2 Xn | 20/21/22,36/38 |
3. HAZARDS IDENTIFICATION
| Most important hazards: | All ingredients are unlikely to leach from pallets. This compound contains small amount of Sn. Sn is harmful by inhalation and if swallowed. |
4. FIRST AID MEASURES
| Inhalation: | Pellets: Not applicable. At elevated temperature: Remove to fresh air. If not breathing: Artificial respiration. If breathing is difficult: Oxygen. Immediately get medical attention. | |
| Skin contact: | Pellets: Not applicable. At elevated temperature: Wash off with plenty of water and soap. Remove contaminated clothing. Get medical attention. | |
| Eye contact: | Wash off with plenty of water with eyelids open for at least 15’. Remove contact lens if worn. Get medical attention. | |
| Ingestion: | Consult a doctor if irritation occurs/persists. | |
| Note to the physician: | ||
5. FIRE FIGHTING MEASURES
| Suitable extinguishing media: | CO2, foam, dry chemical, water spray. | ||
| Specific hazards: | PVC is considered as an auto-extinguisher and incapable of propagating a flame. Avoid dust condition to reduce explosion potential. See also section 10. | ||
| Special protective equipment for fire fighters: | Self-contained breathing apparatus. Full protective clothing. | ||
| Specific methods: | Use water to keep fire-exposed containers cool. | ||
6. ACCIDENTAL RELEASE MEASURES
| Personal precautions: | See section 8. | ||
| Environmental precautions: | Stop source of spill. Do not allow to enter sewerage system and other water bodies. If yes, notify responsible authority of non-floating plastic pellets. Ingredients are unlikely to leach from pellets. | ||
| Methods for cleaning up: | Sweep up spilled pellets and place in suitable container for reuse or disposal. Consult an expert on disposal of recovered pellets and ensure conformity to local regulations. | ||
7. HANDLING AND STORAGE
| Handling: | Maintain proper grounding against static electricity to all installation system. Spilled pellets may cause severe slipping condition. |
| Storage: | Do not store near flame. Do not exceed 70ºC while storing in silos or any other containers. |
8. EXPOSURE CONTROL/PERSONAL PROTECTION
| Chemical name | Cas No. | National occupational exposure limits | ||
| Total dust | 10 mg/m² ACGIH | |||
| Tin compounds | 0.1 mg Sn/m² ACGIH | |||
| Engineering measures to reduce exposure: | If dust condition is over recommendation use local exhaust. | |||
| Personal protection equipment | ||||
| Respiratory protection: | Use NIOSH approved mask if unable to control airborne dust fumes and vapors. In case of decomposition - use gas mask with type B filter in case of release of HCl. | |||
| Hand protection: | Cold pellets - not necessary. Hot pellets - isolated gloves. | |||
| Eye protection: | Cold pellets - not necessary. Hot pellets - face shield. | |||
| Skin & body protection: | Wear suitable protective clothing. | |||
| Hygiene measures: | When using the material, do not eat, drink or smoke. Wash hands prior to breaks or at works’ end; clean face as well. | |||
9. PHYSICAL & CHEMICAL PROPERTIES
| State: | Pellets | Color: | Natural | Odor: | No | ||||||||
| Specific gravity: | 1.32 | Melting pt.: | 170 - 180º C | Decomposition temp.: | 200º C | ||||||||
| Boiling pt.: | Auto ignition temp. | 450º C | Vapor pressure: | None | |||||||||
| Flashing: | 390º C | Explosion risk: | None | Solubility-water: | None | ||||||||
10. STABILITY & REACTIVITY
| Stability: | ( x ) stable ( ) unstable | |||
| Conditions to avoid: | Temperature over 200º C | |||
| Material to avoid: | None | |||
| Hazardous decomposition products: | COX, HCl . Small amounts of oxides of Sn. | |||
| Hazardous polymerization: | ( ) may occur ( x ) will not occur | |||
11. TOXICOLOGICAL INFORMATION
| Acute toxicity: | LD50 - mg/kg | ||||||
| Component Oral (rat): | mg/kg | Dermal (rat): | mg/kg | Skin (rat): | mg/m3 | ||
| Sn compound | >1100 | >1000 | 0.1 | ||||
| Skin Irritation : | None | ||||||
| Eye Irritation : | Dust may cause eye irritation | ||||||
| Ingestion: | |||||||
| Inhalation: | |||||||
| Chronic toxicity: | |||||||
12. ECOLOGICAL INFORMATION
| Details for elimination: | Water insoluble product. Can be separated in wastewater by filtration. | ||
| Performance in ecological sub-system: | PVC is regarded as biologically inert. | ||
| Eco-toxicity: | |||
13. DISPOSAL CONSIDERATIONS:
| Wastes from residues/unused Products: | Dispose of in accordance with local state and federal regulations. |
| Contaminated packing: | Same as waste from residues. |
14. TRANSPORTATION INFORMATION
| ADR/RID – HI/UN No.: | None | Class: | ||||||||
| Proper shipping name: | ||||||||||
| IMDG–UN No. | None | Class: | Marine pollutant: | No | ||||||
| Proper shipping name: | ||||||||||
| MFAG: | None | IMDG page: | Ems: | |||||||
| ICAO- | None | UNI/ID No. | Class: | |||||||
| Proper shipping name: | ||||||||||
15. REGULATORY INFORMATION
Classification according to European directive
on classification of hazardous preparations 91/155/EEC
| Contains: | Not dangerous according to EEC regulation |
| Symbols: | None |
| R-Phrases: | None |
| S-Phrases: | None |
16. OTHER INFORMATION
| Recommended use: | For industrial use only | |||
| Recommended restrictions: | ||||
| Further information contact name: | TERRAFLEX RESHAFIM | |||
| Department: | Tel : 972-4-6065384 | |||